Marker nominal neutral mass
|
446
|
448
|
450
|
464
|
466
|
468
|
---|
[M-H]-(%)
|
445 (100%)
|
447 (52%)
|
449 (92%)
|
463 (70%)
|
465 (100%)
|
467 (100%)
|
---|
Chain cut ions (%)
|
223 (18%)
|
277 (11%)
|
171 (7%)
|
277 (10%)
|
241 (7%)
|
187 (12%)
|
| |
222 (11%)
|
239 (5%)
|
127 (9%)
|
241 (68%)
|
223 (3%)
|
169 (3%)
|
| |
207 (3%)
|
207 (3%)
|
125 (12%)
|
223 (15%)
|
215 (2%)
|
141 (2%)
|
| |
205 (11%)
|
169 (6%)
|
113 (38%)
|
185 (8%)
|
185 (4%)
|
113 (4%)
|
| |
113 (5%)
|
113 (25%)
| |
167 (4%)
|
167 (4%)
| |
| | | | |
113 (28%)
|
113 (7%)
| |
Peripheral cut ions (%)
|
Loss of H
2
O
|
427 (50%)
|
429 (35%)
|
431 (80%)
|
445 (46%)
|
447 (45%)
|
449 (84%)
|
|
Loss of 2H
2
O
|
409 (8%)
|
411 (6%)
|
413 (13%)
|
427 (6%)
|
429 (8%)
|
431 (10%)
|
|
Loss of CO
2
|
401 (95%)
|
403 (100%)
|
405 (100%)
|
419 (100%)
|
421 (45%)
|
423 (25%)
|
|
Loss of CO
2
and H
2
O
|
383 (28%)
|
385 (15%)
|
387 (32%)
|
401 (24%)
|
403 (20%)
|
405 (13%)
|
|
*Loss of CO
2
and 2H
2
O
|
365
|
367
|
369
|
383 (2%)
|
385 (4%)
|
387 (3%)
|
|
*Loss of 3H
2
O
| | | |
409
|
411
|
413
|
Secondary daughter ions (%)
|
357 (5%)
|
331 (3%)
|
307 (5%)
|
347 (5%)
|
349 (4%)
|
349 (1%)
|
| |
329 (11%)
|
305 (3%)
|
291 (7%)
|
319 (5%)
|
321 (2%)
|
323 (2%)
|
| |
261 (3%)
|
359 (2%)
|
295 (5%)
|
295 (6%)
|
297 (3%)
|
309 (2%)
|
| |
241 (3%)
|
289 (3%)
|
281 (5%)
|
281 (5%)
|
281 (3%)
|
297 (6%)
|
| |
233 (5%)
|
245 (3%)
|
279 (9%)
|
279 (5%)
|
279 (15%)
|
281 (3%)
|
| |
207 (11%)
|
125 (6%)
|
263 (7%)
|
267 (5%)
|
261 (3%)
|
279 (5%)
|
| |
177 (11%)
|
123 (3%)
|
261 (5%)
|
249 (6%)
|
251 (3%)
|
269 (5%)
|
| |
123 (5%)
|
121 (3%)
|
169 (5%)
|
195 (10%)
|
195 (2%)
|
263 (8%)
|
| |
109 (11%)
|
111 (5%)
|
111 (5%)
|
141 (1%)
|
141 (2%)
|
251 (4%)
|
| |
97 (16%)
|
97 (5%)
|
97 (8%)
|
127 (9%)
|
123 (4%)
|
243 (2%)
|
| |
83 (11%)
|
59 (3%)
|
83 (5%)
|
121 (6%)
|
113 (5%)
|
215 (4%)
|
| |
59 (11%)
| |
59 (1%)
|
101 (6%)
|
101 (3%)
|
213 (3%)
|
| | | | |
97 (4%)
|
97 (32%)
|
197 (3%)
|
| | | | |
83 (2%)
|
83 (2%)
|
125 (4%)
|
| | | | |
59 (2%)
|
59 (2%)
|
111 (3%)
|
| | | | | | |
98 (2%)
|
| | | | | | |
57 (1%)
|
- *Ions m ay have been obtained from MS3 experiments