|
Standard
|
1
|
2
|
3
|
4
|
5
|
6
|
7
|
8
|
9
|
10
|
11
|
12
|
13
|
14
|
15
|
|---|
|
[M-H]-(%)
|
335 (45%)
|
319 (100%)
|
319 (100%)
|
429 (14%)
|
415 (28%)
|
445 (90%)
|
445 (68%)
|
429 (100%)
|
445 (64%)
|
397 (6%)
|
385 (2%)
|
397 (5%)
|
451 (28%)
|
287 (1%)
|
431 (100%)
|
|
*Chain cut ions (%)
|
219 (15%)
|
219 (80%)
|
203 (3%)
| | | | | | | | | | | | |
| | |
201 (1%)
|
203 (15%)
|
163 (25%)
| | | | | | | | | | | | |
| | |
115 (100%)
|
175 (55%)
|
155 (60%)
| | | | | | | | | | | | |
| | | |
113 (20%)
|
127 (10%)
| | | | | | | | | | | | |
| | | | |
111 (5%)
| | | | | | | | | | | | |
|
*Peripheral cut ions (%)
|
Loss of H
2
O
|
317 (16%)
|
301 (60%)
|
301 (55%)
| | |
427 (50%)
| |
401 (30%)
|
401 (28%)
|
379 (10%)
|
367 (18%)
|
379 (5%)
| |
269 (1%)
|
413 (1%)
|
| |
Loss of 2H
2
O
|
299
| | | | | | | | | | | | | | |
| |
Loss of CO
2
|
291 (2%)
|
275 (20%)
|
275 (4%)
| | |
401 (1%)
|
401 (35%)
| | | | | | | | |
| |
Loss of CO
2
and H
2
O
|
273 (6%)
|
257 (70%)
|
257 (80%)
| | | | | | | | | | | | |
| |
*Loss of CO
2
and 2H
2
O
| | | | | | | | | | | | | | | |
| |
*Loss of 3H
2
O
| | | | | | | | | | | | | | | |
|
Secondary daughter ions (%)
|
189 (1%)
|
167 (5%)
|
291 (1%)
|
414 (5%)
|
400 (78%)
|
295 (70%)
|
386 (52%)
|
163 (100%)
|
386 (43%)
|
309 (5%)
|
273 (3%)
|
295 (5%)
|
436 (10%)
|
187 (5%)
|
399 (100%)
|
| | |
163 (1%)
|
149 (2%)
|
171 (1%)
|
163 (100%)
|
175 (13%)
|
149 (90%)
|
179 (60%)
|
135 (20%)
|
179 (50%)
|
213 (15%)
|
259 (25%)
|
253 (6%)
|
241 (21%)
|
173 (10%)
|
393 (40%)
|
| | |
145 (2%)
|
121 (20%)
|
107 (1%)
|
135 (8%)
|
149 (100%)
|
136 (100%)
|
135 (100%)
|
218 (5%)
|
166 (20%)
|
201 (30%)
|
255 (15%)
|
211 (12%)
|
227 (62%)
|
159 (18%)
|
373 (40%)
|
| | |
99 (1%)
|
99 (1%)
|
59 (1%)
| |
121 (90%)
|
121 (20%)
|
107 (25%)
|
123 (5%)
|
135 (100%)
|
173 (37%)
|
213 (20%)
|
159 (20%)
|
223 (48%)
|
145 (28%)
|
355 (40%)
|
| | |
95 (1%)
|
59 (1%)
| | | | | | |
122 (25%)
|
159 (35%)
|
173 (47%)
|
161 (15%)
|
213 (55%)
|
119 (15%)
|
337 (20%)
|
| | |
71 (1%)
| | | | | | | |
107 (25%)
|
107 (90%)
|
161 (52%)
|
147 (20%)
|
199 (57%)
|
105 (20%)
|
223 (40%)
|
| | |
59 (1%)
| | | | | | | | |
81 (68%)
|
159 (75%)
|
107 (25%)
|
187 (100%)
|
95 (36%)
|
85 (40%)
|
| | | | | | | | | | | |
69 (100%)
|
149 (40%)
|
105 (15%)
|
185 (52%)
|
93 (28%)
| |
| | | | | | | | | | | | |
147 (72%)
|
95 (38%)
|
171 (55%)
|
81 (58%)
| |
| | | | | | | | | | | | |
107 (100%)
|
93 (17%)
|
71 (86%)
|
69 (100%)
| |
| | | | | | | | | | | | |
81 (82%)
|
83 (25%)
| | | |
| | | | | | | | | | | | | |
81 (40%)
| | | |
| | | | | | | | | | | | | |
36 (100%)
| | | |
- *This terminology is specific to fatty acid fragmentation.
- 5S,6S-(7E,9E,11Z,14Z)-dihydroxyeicosatetraenoic acid (1), 15S-Hydroxy-(5Z,8Z,11Z,13E)-eicosatetraenoic acid (2) and 8R-Hydroxy-(5Z,9E,11Z,14Z)-eicosatetraenoic acid (3) (Table 6), α-tocopherol (4) γ-tocopherol (5), 13-(6-hydroxy-2,7,8-trimethylchroman-2-yl)-2,6,10-trimethyltridecanoic acid (6), 16-(4,5-dimethyl-3,6-dioxo cyclohexa-1,4-dienyl)-2,6,10,14-tetramethylhexadecanoic acid (7), 6-hydroxy-2,7-dimethyl-2-(4,8,12-trimethyltridecyl)chroman-8-carbaldehyde (8), 6-hydroxy-2,7-dimethyl-2-(4,8,12-trimethyltridecyl)chroman-8-carboxylic acid (9), calciferol (10), cholecalciferol (11), ergosterol (12), phylloquinone (13), retinol (14) and 3β,7α-dihydroxy-5-cholestenoic acid (15).
